This study reveals the effect of aerosols and water vapor on downward longwave radiation in the high mountain region of Musala peak, Bulgaria. The investigated period is 01/01/2017 (Jan. 1st 2017) – 30/09/2019 (Sep. 30th 2019). Statistical methods are the main tool for discovering the relationships between the different elements. The results indicate that air temperature is the leading factor for downward longwave radiation, specific humidity, and amount of aerosols in the air. That is why, in order to reveal the pure relationship between downward longwave radiation, specific humidity and amount of aerosols in the atmosphere, the air temperature was cleared from the data series. After this procedure, the results show that specific humidity has a significant influence on the downward longwave radiation flux, and an increase of 1% of the specific humidity results in an increase of about 12-15% in the values   of the downward longwave radiation. At air temperatures around 0ºC the influence of water vapor on the downward longwave flux is highest, which is due to the phase transitions of the water – a process during which release/absorption of radiation in the longwave spectrum occurs. The amount of aerosols in the atmosphere also has a significant effect on this type of radiation, and an increase of 1% of the amount of aerosols in the air at air temperatures above –5.5°C results in an increase of the downward longwave radiation of about 2-4%. The findings of this study show that coarser and opaque aerosol particles have a stronger effect on downward longwave radiation. In the area of Musala peak, as the air temperature rises, there is an increase in the amount of aerosols in the air, a decrease in their size, and a transition from transparent to opaque aerosols. The combination of these different tendencies causes the influence of aerosols on downward longwave radiation to be strongest in the middle temperature interval – air temperatures between –5.5°C and +5.5°C. Due to the increased total amount of aerosols and increased amount of opaque aerosols, their influence on downward longwave radiation is significant also at air temperatures above 5.5°C.